降冰片烯类化合物的合成与表征%The Synthesis and Characterization of the Norbornene and Its Derivates
河南省科学院化学研究所有限公司,河南郑州,450002 河南省科学院化学研究所有限公司,河南郑州450002;河南金上化成化工科技有限公司,河南郑州450002
2018-02-11
混合碳五 叔丁基邻苯二酚 降冰片烯
选取叔丁基邻苯二酚和[Cu2(dppm)2(C7H7N)(μ-NO3)](NO3)为催化剂,丙烯类化合物和混合碳五为原料合成降冰片烯衍生物.研究表明,在-15℃ ~5℃ 温度下,混合碳五中的环戊二烯和丙烯类化合物经Diels-Alder反应得到目标产物,收率可达74.1% ~87.8%.%In this paper,acrylic compounds and C5 were adopted as raw materials,and tert-butyl catechol and [Cu2(dppm)2(C7H7N)(μ-NO3)](NO3) were selected as catalysts to synthesis norbornene and its derivates. Ex-perimental research have shown that the target products were obtained through the Diels-Alder reaction between cy-clopentadiene in C5 and acrylic compounds with 74.1% ~87.8% yield at the temperature of -15℃ ~5℃.
